Activation and Catalytic Reactions of Saturated Hydrocarbons by A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov

By A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov

Hemistry is the technological know-how approximately breaking and forming of bonds among atoms. essentially the most very important tactics for natural chemistry is breaking bonds C–H, in addition to C–C in a variety of compounds, and essentially, in hydrocarbons. between hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane and so forth. ), are specially appealing as substrates for chemical changes. it's because, at the one hand, alkanes are the most parts of oil and common fuel, and for that reason are the valuable feedstocks for chemical undefined. nonetheless, those components are recognized to be the fewer reactive natural compounds. Saturated hydrocarbons can be referred to as the “noble gases of natural chemistry” and, if this is the case, the 1st consultant in their kinfolk – methane – can be in comparison with super inert helium. As in all comparisons, this parallel among noble gases and alkanes isn't totally exact. certainly the differences of alkanes, together with methane, were identified for a very long time. those reactions contain the interplay with molecular oxygen from air (burning – the most resource of energy!), in addition to a few mutual interconversions of saturated and unsaturated hydrocarbons. although, these kinds of alterations happen at increased temperatures (higher than 300–500 °C) and tend to be characterised through a scarcity of selectivity. The conversion of alkanes into carbon dioxide and water in the course of burning is a very precious strategy – yet now not from a chemist perspective.

Show description

Read Online or Download Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes PDF

Best inorganic books

Paramagnetic Resonance of Metallobiomolecules

Paramagnetic transition steel ions give you the chance for program of a wide selection of spectroscopic recommendations. even though spectroscopic concepts should not in addition referred to as traditional nuclear magnetic resonance (NMR), they supply designated info established at the energetic website itself. This booklet describes the appliance of paramagnetic resonance recommendations to a couple of vital platforms in metallobiochemistry.

Transition Metal Compounds

Describing all elements of the physics of transition steel compounds, this booklet offers a accomplished review of this detailed and numerous classification of solids. starting with the elemental ideas of the physics of strongly correlated electron structures, the constitution of transition steel ions, and the behaviours of transition steel ions in crystals, it is going directly to hide extra complex subject matters corresponding to metal-insulator transitions, orbital ordering, and novel phenomena corresponding to multiferroics, structures with oxygen holes, and high-Tc superconductivity.

Catalysis by Ceria and Related Materials

This publication follows the 2002 version of Catalysis through Ceria and similar fabrics, which used to be the 1st booklet completely dedicated to ceria and its catalytic homes. within the ten years because the first variation a big quantity of labor has been performed within the box, and ceria has won a well-liked place in catalysis as some of the most invaluable fabric for numerous purposes.

Extra resources for Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes

Example text

1. C. RADIOLYSIS The interaction of high-energy irradiation with alkanes leads, at the first stage of the process, to the excitation of the hydrocarbon molecule [3a]. Furthermore, the excited molecule decomposes to generate free radicals and carbenes. Radiolysis of methane produces ethane, ethylene, and higher hydrocarbons: Transformations in the Absence of Metals 25 Pulse radiolysis of methylcyclohexane (MCH) gives rise to the formation of the solvent radical cation, but in argon-saturated MCH, the olefinic fragment cation is obtained [3b].

Ford, P. C. J. Am. Chem. Soc. 1985, 107, 2355. ; Dedieu, A. Theor. Chim. Acta 1982, 61, 587. ; Nakamura, S. Nouv. J. Chim. 1984, 8, 317. ; Green, M. L. H. J. Organomet. Chem. 1983, 250, 395. (b) Crabtree, R. ; Hamilton, D. G. Adv. Organomet. Chem. 1988, 28, 299. (c) Ginzburg, A. ; Bagatur’yants, A. A. Metalloorg. Khim. 1989, 2, 249 (in Russian). (d) Crabtree, R. H. Acc. Chem. Res. 1990, 23, 95. (e) Crabtree, R. H. Angew. , Int. Ed. Engl. 1993, 32, 789. (f) Heinekey, D. ; Oldham, W. , Jr. Chem.

Ford, P. C. J. Am. Chem. Soc. 1985, 107, 2355. ; Dedieu, A. Theor. Chim. Acta 1982, 61, 587. ; Nakamura, S. Nouv. J. Chim. 1984, 8, 317. ; Green, M. L. H. J. Organomet. Chem. 1983, 250, 395. (b) Crabtree, R. ; Hamilton, D. G. Adv. Organomet. Chem. 1988, 28, 299. (c) Ginzburg, A. ; Bagatur’yants, A. A. Metalloorg. Khim. 1989, 2, 249 (in Russian). (d) Crabtree, R. H. Acc. Chem. Res. 1990, 23, 95. (e) Crabtree, R. H. Angew. , Int. Ed. Engl. 1993, 32, 789. (f) Heinekey, D. ; Oldham, W. , Jr. Chem.

Download PDF sample

Rated 4.80 of 5 – based on 12 votes